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Dec 16, 2023

PAI resin employed in cam sprocket

PlasticsToday Staff | Oct 29, 2015 A polyamide-imide (PAI) resin from Solvay

PlasticsToday Staff | Oct 29, 2015

A polyamide-imide (PAI) resin from Solvay Specialty Polymers (Alpharetta, GA) has been used to replace conventional metal in the fabrication of an innovative cam sprocket design for the Polimotor 2 project. Solvay is the principal material sponsor for this highly anticipated technical project, which aims to design and manufacture a next-generation, all-plastic engine for competitive racing in 2016.

"Solvay's Torlon PAI played a vital role in the success of our first Polimotor engine during the early 1980s; and the breadth, performance and versatility of the company's materials technology has definitely expanded since then," said project leader Matti Holtzberg, who is also president of Composite Castings (West Palm Beach, FL). "Solvay's continuing advances offer the basis for even greater innovation in Polimotor 2 today, where its carbon-fiber filled Torlon PAI enabled development of a mechanically strong, but extremely lightweight cam shaft sprocket. This is only the first of several new breakthrough applications using Solvay's advanced materials technology that we expect to announce in the coming months."

Cam sprockets are attached to one end of the cam shaft in an automotive combustion engine and, along with the timing belt, help maintain timing between the cam shaft and crankshaft. Despite constant exposure to high torque, extreme temperatures and vibration, as well as dirt, automotive fluids and road salt, cam sprockets must reliably deliver precise timing control to maintain optimal engine performance. If these sprockets overheat, chip, lose their shape or fail to perform reliably under load, everything from the crank to the pistons can quickly cease to work properly.

Cam sprockets are typically made from sintered steel, aluminum or occasionally thermoset phenolic polymers. However, Polimotor 2 opted to mold its engine's spur tooth cam sprockets using Solvay's 30 percent carbon fiber-reinforced Torlon 7130 PAI - an ultra-high performance grade launched by Solvay long after Polimotor's earlier iteration during the 1980s.

As a class of materials, Solvay's Torlon PAI delivers the highest strength, stiffness and fatigue resistance of any thermoplastic technology up to 525° F (275° C). Torlon 7130 PAI, in particular, delivers the portfolio's most optimal balance of these mechanical properties, with a specific strength of 5.4 x 105 in-lbf/lb (1.4 105 J/kg) and specific stiffness 6 x 107 in-lbf/lb (15 106 J/kg). Stainless steel, in contrast, delivers specific strength and stiffness of 3.1 x 107 in-lbf/lb (0.8 106 J/kg), and 9.7 x 107 in-lbf/lb (24 106 J/kg), respectively.

In practical terms, this allows the Polimotor 2 cam sprocket fabricated from Torlon 7130 PAI to deliver comparable mechanical properties with a 75 percent weight reduction over a similarly sized stainless steel cam sprocket that weighs 2.4-lb (1.1 kg).

Unlike metals, Torlon 7130 PAI does not conduct heat, helping to promote longer belt life. It also eliminates potential chipping of the sprocket, which can be a concern when using phenolic materials because they are more brittle. Lastly, Solvay's high-performance PAI delivers excellent fatigue resistance and outstanding wear performance at elevated pressures and velocities, thereby decreasing noise and vibration, and offers broad chemical resistance to automotive fluids.

"The innovative selection of high-strength, lightweight, fatigue-resistant Torlon PAI over traditional sintered steel or aluminum was critical to our ability to develop a new, state-of-the art valve train drive system for Polimotor 2," said Fraser Lacy, senior engineering specialist for Gates Corp.

Torlon PAI and other Solvay high-performance polymers are seeing strong adoption as a metal replacement option in automotive engines as OEMs move to downsize and downspeed them. Solvay's advanced polymers offer higher efficiency through reduction of weight to enable OEMs to comply with tougher corporate average fuel economy (CAFÉ) regulations and stricter CO2 emission standards, both of which are considered top priorities for the automotive industry over the next decade.

"One of the highest performing polymers in Solvay's automotive portfolio, Torlon PAI has a proven track record of success in commercial automatic transmissions and dual-clutch transmissions, where higher pressure and velocities require higher temperature materials with excellent strength, stiffness and fatigue resistance," said Brian Baleno, global automotive business manager for Solvay Specialty Polymers. "One notable area is metal replacement for needle bearings where Torlon® PAI saves both weight and space, allowing transmissions to be smaller than comparable aluminum castings, which helps reduce CO2 emissions and lower cost."

The Polimotor 2 project aims to develop an all-plastic, four-cylinder, double-overhead CAM engine that weighs between 138 to 148 lb. (63-67 kg), or about 90 lb. (41 kg) less than today's standard production engine. In addition to the current cam sprocket application, Holtzberg's groundbreaking program will leverage Solvay's advanced polymer technology to develop up to ten engine parts. These include a water pump, oil pump, water inlet/outlet, throttle body, fuel rail and other high-performance components. Solvay materials targeted for use encompass Amodel polyphthalamide (PPA), KetaSpirepolyetheretherketone (PEEK), AvaSpire polyaryletherketone (PAEK), Radel polyphenylsulfone (PPSU), Ryton polyphenylene sulfide (PPS) and Tecnoflon VPL fluoroelastomers.

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